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Periodic table › Copper

29Cu63.546

Copper — Cu

Transition Metal · Group 11 · Period 4

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1. Identity and classification

Red-orange metallic solid with high ductility, malleability, and thermal/electrical conductivity

Name and symbol
Copper (Copper) · Cu
Atomic number
29
Relative atomic weight / mass number
63.546 ± 0.003
Group · period · block
11 · 4 · d
Category
Transition Metal
State near room temperature
Solid
Stable isotopes
At least one stable isotope
CAS number
7440-50-8

Square brackets [A] indicate a representative isotope mass number, not an average atomic weight. Neutron counts differ between isotopes.

2. Atomic structure and electron configuration

Protons · electrons in a neutral atom
29 · 29
Neutrons in reference isotope
34 (63Cu)
Full electron configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹
Abbreviated configuration
[Ar]4s¹ 3d¹⁰
Electrons per shell
2, 8, 18, 1
Listed oxidation states
+2, +1
Electronegativity
1.9 (Pauling)
First ionization energy
745.446 kJ/mol · 7.726 eV
Electron affinity
118.484 kJ/mol
Covalent radius
132 pm
van der Waals radius
140 pm

Configurations of superheavy elements may include theoretical predictions. Different definitions of atomic radius are not interchangeable.

3. Physical and thermal properties

Density
8.933 g/cm³
Melting point
1357.77 K · 1084.62 °C · 1984.316 °F
Boiling point
2835 K · 2561.85 °C · 4643.33 °F
Crystal structure
FCC
Specific heat
0.385 J/(g·K)
Thermal conductivity
401 W/(m·K)
Enthalpy of fusion
13.26 kJ/mol
Enthalpy of vaporization
300.4 kJ/mol
Magnetic ordering
Diamagnetic
Mohs hardness
3
Speed of sound
3810 m/s

Density and structure depend on temperature, pressure and allotrope. 25°C is a room-temperature reference, not STP. Unestablished values are not zero.

4. Chemical behavior and compounds

Copper does not liberate hydrogen from dilute non-oxidizing acids; oxidizing acids can dissolve it.

Selected compounds: CuSO₄·5H₂O (Blue vitriol / Copper(II) sulfate) · CuO (Copper(II) oxide) · Cu₂O (Cuprite) · CuCl₂

Reaction reference

Copper oxidizes slowly in air; surface products depend on environmental conditions.

No reaction with ordinary cold water.

5. Isotopes

IsotopeStatusNatural abundanceHalf-life
63CuStable69.15%Stable
64CuRadioactive—12.7006 h
65CuStable30.85%Stable

Half-life units: s seconds, m minutes, h hours, d days, Y years. A dash means no natural-abundance value is given, not zero. Listed records are selected ground states; metastable states are distinct.

6. Discovery and occurrence

Discovery
Known since antiquity; no exact discovery year
Scientists associated with discovery
Known since antiquity
Location
Middle East & Cyprus
Origin
Natural
Listed crustal abundance
60 ppm
Minerals and naming reference

Chalcopyrite (CuFeS₂), Bornite (Cu₅FeS₄), Chalcocite (Cu₂S), Malachite, Azurite, Native Copper

From Latin 'aes Cyprium' (metal of Cyprus), shortened to 'cuprum'

7. Applications

Household electrical wiring, plumbing pipes, brass and bronze hardware, coins, cookware

Detailed applications by field
everyday
Household electrical wiring, plumbing pipes, brass and bronze hardware, coins, cookware
industry
Brass (Cu-Zn) and bronze (Cu-Sn) alloys, industrial heat exchangers, marine anti-fouling hulls
electronics
Printed circuit board (PCB) traces, microprocessor interconnects, high-frequency coaxial cables, electromagnets
medicine
Antimicrobial copper touch surfaces in hospitals, copper intrauterine devices (IUDs)
energy
EV traction motors, solar inverter busbars, high-voltage power transmission grids, wind generators
aerospace
Regeneratively cooled liquid rocket engine combustion chambers (e.g., CuCrZr alloys)
agriculture
Bordeaux mixture and copper sulfate fungicides for vineyards and orchards
science
Cu K-alpha X-ray tubes for X-ray crystallography; YBCO high-temperature cuprate superconductors

8. Biological role and safety

Hazard depends on the isotope, chemical form, dose and exposure route.

Elemental substances, ions, compounds and radioisotopes can have different health effects. This is an educational reference; laboratory work requires the material safety data sheet and trained supervision.

Biological role reference

Essential cofactor in cytochrome c oxidase (respiration), superoxide dismutase (antioxidant defense), and tyrosinase; forms hemocyanin oxygen carrier in mollusks and arthropods.