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Periodic table › Thorium

90Th232.04

Thorium — Th

Actinoid · Group Actinoid (f-block) · Period 7

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1. Identity and classification

Dense, silvery, radioactive f-block metal that tarnishes rapidly in air

Name and symbol
Thorium (Thorium) · Th
Atomic number
90
Relative atomic weight / mass number
232.04 ± 0.01
Group · period · block
Actinoid (f-block) · 7 · f
Category
Actinoid
State near room temperature
Solid
Stable isotopes
No stable isotopes
CAS number
7440-29-1

Square brackets [A] indicate a representative isotope mass number, not an average atomic weight. Neutron counts differ between isotopes.

2. Atomic structure and electron configuration

Protons · electrons in a neutral atom
90 · 90
Neutrons in reference isotope
142 (232Th)
Full electron configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶ 6d² 7s²
Abbreviated configuration
[Rn]7s² 6d²
Electrons per shell
2, 8, 18, 32, 18, 10, 2
Listed oxidation states
+4
Electronegativity
1.3 (Pauling)
First ionization energy
586.631 kJ/mol · 6.08 eV
Electron affinity
Not established
Covalent radius
206 pm
van der Waals radius
237 pm

Configurations of superheavy elements may include theoretical predictions. Different definitions of atomic radius are not interchangeable.

3. Physical and thermal properties

Density
11.72 g/cm³
Melting point
2023 K · 1749.85 °C · 3181.73 °F
Boiling point
5061 K · 4787.85 °C · 8650.13 °F
Crystal structure
FCC
Specific heat
0.113 J/(g·K)
Thermal conductivity
54 W/(m·K)
Enthalpy of fusion
13.81 kJ/mol
Enthalpy of vaporization
514 kJ/mol
Magnetic ordering
Paramagnetic
Mohs hardness
3
Speed of sound
2490 m/s

Density and structure depend on temperature, pressure and allotrope. 25°C is a room-temperature reference, not STP. Unestablished values are not zero.

4. Chemical behavior and compounds

The +3 state is common in this series, with important element-specific exceptions.

Selected compounds: ThO / Th₂O₃ (Oxide) · ThClₙ (Chloride) · ThFₙ (Fluoride)

Reaction reference

Many members oxidize in air; behavior depends on the element and oxidation state.

Water reactivity varies across this series and with surface conditions.

5. Isotopes

IsotopeStatusNatural abundanceHalf-life
230ThRadioactive0.02%7.54E+4 Y
232ThRadioactive99.98%1.40E10 Y

Half-life units: s seconds, m minutes, h hours, d days, Y years. A dash means no natural-abundance value is given, not zero. Listed records are selected ground states; metastable states are distinct.

6. Discovery and occurrence

Discovery
1828 CE
Scientists associated with discovery
Jöns Jacob Berzelius
Location
Sweden (Stockholm)
Origin
Natural
Listed crustal abundance
Not established
Minerals and naming reference

Monazite ((Ce,La,Nd,Th)PO₄), Thorite (ThSiO₄), Thorianite

Named from scientific/historical roots associated with Thorium (Th), discovered or characterized by Jöns Jacob Berzelius.

7. Applications

Thorium fuel cycle breeder reactors (especially relevant for India's 3-stage nuclear program using abundant monazite sands), TIG welding electrodes

Detailed applications by field
everyday
Thorium fuel cycle breeder reactors (especially relevant for India's 3-stage nuclear program using abundant monazite sands), TIG welding electrodes
industry
Used in actinoid processing, specialized alloys, and chemical manufacturing (Thorium fuel cycle breeder reactors (especially relevant for India's 3-stage nuclear program using abundant monazite sands), TIG welding electrodes).
electronics
Applied in electronic components, semiconductors, or functional coatings where Thorium's electronic structure ([Rn] 6d² 7s²) provides target conductivity.
medicine
Restricted to controlled nuclear medicine or fundamental radiochemical research.
energy
Utilized in power generation, battery materials, catalysts, or nuclear technology involving Thorium.
aerospace
High-performance materials, structural alloys, or space instrumentation utilizing Thorium.
agriculture
Not used in agriculture due to radioactivity or heavy-metal toxicity.
science
Spectroscopic standard, crystallography, and quantum chemistry studies of Period 7 f-block elements.

8. Biological role and safety

Hazard depends on the isotope, chemical form, dose and exposure route.

Elemental substances, ions, compounds and radioisotopes can have different health effects. This is an educational reference; laboratory work requires the material safety data sheet and trained supervision.

Biological role reference

Classified as highly radioactive / synthetic in human and biological systems.